Houseane
Housane or bicyclo[2.1.0]pentane is a saturated cycloalkane with the formula C5H8. It is a colorless volatile liquid at room temperature. It was named "housane" because of its shape. Structurally, the molecule consists of cyclopropane fused to cyclobutane. The synthesis of molecules containing multiple … See more The first synthesis of housane was reported by Criegee in 1957, where housane was obtained from the pyrolysis of 2,3-diazabicyclo[2.2.1]hept-2-ene. Housane can be prepared in several steps starting with See more The two rings are fused in a cis configuration—this meso compound formally has (1R,4S) absolute stereochemistry. The small size of the two rings prevents the … See more WebStudy with Quizlet and memorize flashcards containing terms like acyclic alkanes, acrylic alkanes, they have the max number of hydrogens per C pi bond would be unsaturated and more.
Houseane
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WebLips et al. described the addition of phospha-alkyne PC-t Bu to an NHC-coordinated trisilacyclopropylidene, Si 3 Mes 4 NHC (93), resulting in the formation of a heavier analog (94′) of a bicyclo[2.1.0]pentane, a so-called housane. 290 The NHC used was 1,3-diisopropylimidazol-2-ylidene.In housane 94′, the folding angle is 88.46(2)°, as expected …
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WebA method for producing a carbodiimide compound, comprising a carbodiimide production step of reacting an aliphatic tertiary isocyanate compound (A) in the presence of an organic alkali metal compound
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